Wang, Hui (2002) Response of a PVC lignin blended building material to fungi attack. Masters thesis, Concordia University.
Poly vinyl chloride (PVC) products are susceptible to biological attack. To study this problem, lignin was considered as a material in blend with PVC. Lignin is a renewable, naturally occurring compound and is obtained as a by-product of pulping processes. At present, extensive research has been performed to explore the utilization of lignin. This research studies the feasibility of partially replacing a copolymer of vinyl chloride-vinyl acetate (VC-VAc) by lignin in flooring formulations and evaluates the effects of lignin on the resistance of these formulations to fungi attack. The lignin utilized in the study was an organosolv lignin-Alcell lignin. To accomplish the objectives, a series of PVC controls and PVC-lignin blends with various plasticizers were inoculated with fungi. After a 28-day incubation, the changes in chemical structure were analyzed by Fourie Transform Infrared (ATR/FTIR) spectroscopy. Optical stereomicroscopy and optical microscopy were employed to observe the changes at the surface. This research is the original assessment of the resistances of PVC-lignin blends to biodegradation. After a series of experiments, it was found that all fungi species grew on every composite and showed similar abilities of growth. PVC and PVC-lignin blends are susceptive to fungi attack and plasticizers are the main targets of fungi attack; the susceptibility of the plasticizers to biodegradation in descendent order is: Di-ethylene glycol di-benzoate ( Benzoflex 2-45 ) > Alchil sulphonate ( Mesamoll ) > Di-octyl phthalate ( DOP ) > Tricresyl phospate ( Lindol ). Lindol is the most suitable plasticizer for the formulation of PVC-lignin flooring; Alcell lignin is biodegradable; the presence of Alcell lignin in the complex interactive system PVC-lignin-additives increases the biodegradability of polymeric materials.
|Divisions:||Concordia University > Faculty of Engineering and Computer Science > Building, Civil and Environmental Engineering|
|Item Type:||Thesis (Masters)|
|Pagination:||xiv, 115 leaves : ill. ; 29 cm.|
|Degree Name:||Theses (M.A.Sc.)|
|Program:||Building, Civil and Environmental Engineering|
|Thesis Supervisor(s):||Elektorowicz, Maria|
|Deposited By:||Concordia University Libraries|
|Deposited On:||27 Aug 2009 13:22|
|Last Modified:||08 Dec 2010 10:22|
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