Bird, Peter H. and Wallbridge, M. G. H. (1965) A study of metal borohydrides. The reaction of aluminium borohydride with various ligand molecules. Journal of the Chemical Society . pp. 3923-3928. ISSN 0368-1769
- Published Version
Official URL: http://dx.doi.org/10.1039/JR9650003923
The reactions of aluminium borohydride with several Lewis bases, containing donor atoms from Groups V and VI, have been studied. All the bases react initially to form 1 : 1 adducts, and those containing nitrogen or phosphorus as the donor atom then react further until 4 equivalents of ligand have been consumed; the products are then derivatives of aluminium hydride, L+A1H3 (where L = ligand) and borane, L+BH,. The infrared and the proton and llB nuclear magnetic resonance (n.m.r.) spectra of the products have been recorded, and are discussed in relation to the structure of the adducts. In addition, a comparison of the behaviour of aluminium borohydride with that of the boron hydrides is made.
|Divisions:||Concordia University > Faculty of Arts and Science > Chemistry and Biochemistry|
|Authors:||Bird, Peter H. and Wallbridge, M. G. H.|
|Journal or Publication:||Journal of the Chemical Society|
|Digital Object Identifier (DOI):||10.1039/JR9650003923|
|Deposited By:||DANIELLE DENNIE|
|Deposited On:||15 Jun 2011 19:57|
|Last Modified:||24 Aug 2016 21:26|
H. I. Schlesinger, R. T. Sanderson, and A. B. Burg, J . Amer. Chern. SOC., 1940,62, 3421.
L. Taylor, US. Dept. Comm., Office Tech. Serv., 1961 A.D., 256, 887, pp. 30-32.
J. K. Ruff, Inorg. Chew., 1963, 2, 515.
N. N. Greenwood, A. Storr, and M. G. H. Wallbridge, Proc. Chem. Soc., 1962, 249.
R. A. Ogg and J. D. Ray, Discuss. Furaday Soc., 1955, 19, 239.
J. Y. Beach and S. H. Bauer, J. Amer. Chem. SOC., 1940, 62, 3440; S. H. Bauer, ibid., 1950, 72, 622.
W. C. Price, J. Chenz. Phys., 1949, 17, 1044.
A. R. Emery and R. C. Taylor, Spectrochim. Ada, 1960, 16, 1465.
G. W. Frazer, N. N. Greenwood, and B. P. Straughan, J., 1963, 3742.
T. P. Onak, H. Landesman, R. E. Williams, and I. Shapiro, J . Phys. Chem., 1959, 63, 1533.
A. B. Burg and H. I. Schlesinger, J . Amer. Chem. SOC., 1937, 59, 780.
P H. C. Brown, U.S.P. 2,860,167/1958.
A. B. Burg and R. I. Wagner, J. Amer. Chem. SOC., 1953, 75, 3872.
F. G. A. Stone and A. B. Burg, J. Amer. Chem. SOC., 1954, 76, 386.
H. I. Schlesinger and A. B. Burg, J . Amer. Chem. SOC., 1938, 60, 290.
F. G. A. Stone, Chem. Rev., 1958, 58, 101.
W. A. G. Graham and F. G. A. Stone, J . Inorg. Nuclear Chem., 1956, 3, 164.
L. H. Long and J. F. Sackman, Trans. Faraday SOC.1, 957, 53, 1606.
L. H. Long and J. F. Sackman, Trans. Faraday SOC., 1956, 52, 1201.
H. C. Brown, H. I. Schlesinger, and E. K. Hyde, J . Anzer. Chem. SOC.1, 953, 75, 209.
H. P. Treffers and I,. P. Hammett, J. Arne?. Chem. Soc., 1937, 59, 1708.
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