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Assessing the Emerging Environmental Concerns from Bio-originated Organic Pollutants in Cropping Systems


Assessing the Emerging Environmental Concerns from Bio-originated Organic Pollutants in Cropping Systems

Cai, Mengfan (2023) Assessing the Emerging Environmental Concerns from Bio-originated Organic Pollutants in Cropping Systems. PhD thesis, Concordia University.

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Agriculture plays a significant role in achieving the goal of carbon neutrality and emission reduction through practices such as crop residue management. Crop residues can be utilized to produce biodegradable mulches (BMs), which can increase crop production and carbon sequestration potential. However, agricultural health and safety are facing new challenges, particularly concerning bio-originated organic pollutants in cropping systems, including biogenic volatile organic compounds (BVOCs) and biodegradable microplastics (BMPs). The main purpose of the research presented in this dissertation is to assess these emerging environmental concerns, including the appropriate assessment of BVOC emissions and the degradation and fragmentation of BMs.

BVOC emissions were generally influenced by various factors, including temperature, drought, solar radiation, humidity, nutrient availability, carbon dioxide (CO2), ozone (O3), etc. Among these factors, growth length, air temperature, solar radiation, and leafage were found to be the most important variables affecting the spatial-temporal variations of methanol (MeOH) emissions from spring wheat during the growing period in a Canadian province. The seasonality of MeOH emissions was positively correlated with concentrations of carbon monoxide (CO), filterable particulate matter (FPM), and coarse particulate matter (PM10), but negatively related to nitrogen dioxide (NO2) and O3. Compared with paper mulch, bioplastic mulch contributed a higher amount of aromatic structure-containing chemicals and carboxylic acids, to the water environment, but released fewer and smaller plastic particles. After entering the soil-water environment, the rough microstructure and oxygenated functional groups on BMP surfaces played a crucial role in the adsorption of aromatic compounds and heavy metals from soils.

Scientometric analysis can provide researchers with an in-depth understanding of BVOC emission mechanisms, while also offering decision-makers insights into emission mitigation and environmental management. The newly developed BVOC assessment approach, designed to evaluate the biogenic MeOH emitted from crops during growing seasons, can help uncover the relationships between BVOC emissions and key influencing factors. The characterization and quantification of BMPs in cropping systems focused on examining the fragmentation and degradation of BMPs under UV irradiation using visual inspection and quantitative analysis. This dissertation offers scientific support for researching and further developing the impact of BVOC emissions and BMP generation on environmental management.

Divisions:Concordia University > Gina Cody School of Engineering and Computer Science > Building, Civil and Environmental Engineering
Item Type:Thesis (PhD)
Authors:Cai, Mengfan
Institution:Concordia University
Degree Name:Ph. D.
Program:Civil Engineering
Date:3 July 2023
Thesis Supervisor(s):An, Chunjiang
Keywords:scientometric analysis, biogenic volatile organic compounds, methanol emission, spring wheat, biodegradable microplastics, UV irradiation, particle size
ID Code:992910
Deposited By: Mengfan Cai
Deposited On:14 Nov 2023 19:47
Last Modified:14 Nov 2023 19:47


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