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Spectroscopic studies on derivatives of aluminium borohydride

Title:

Spectroscopic studies on derivatives of aluminium borohydride

Davies, N. and Bird, Peter H. and Wallbridge, M. G. H. (1968) Spectroscopic studies on derivatives of aluminium borohydride. Journal of the Chemical Society A: Inorganic, Physical, Theoretical (9). pp. 2269-2272. ISSN 0022-4944

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Official URL: http://dx.doi.org/10.1039/J19680002269

Abstract

The assignment of group frequencies in the i.r. spectra of derivatives of aluminium borohydride has been made by the use of aluminium borodeuteride. Variations in the spectra with the change of ligand are discussed. The properties of the compounds in solutions have been studied using 1H n.m.r. spectroscopy, and data obtained over a range of temperature indicate that the 1 : 1 adducts with trimethylamine and trimethylphosphine dissociate in solution, and probably exist in equilibrium with both the 1 : 2 adducts, e.g. Al(BH4)3,2NMe3 and free aluminium borohydride

Divisions:Concordia University > Faculty of Arts and Science > Chemistry and Biochemistry
Item Type:Article
Refereed:Yes
Authors:Davies, N. and Bird, Peter H. and Wallbridge, M. G. H.
Journal or Publication:Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Date:1968
ID Code:7657
Deposited By:DANIELLE DENNIE
Deposited On:15 Jun 2011 15:44
Last Modified:15 Jun 2011 15:44
References:
1 P. H. Bird and M. G. H. Walibridge, J . Chem. Soc., 1965,

2 P. H. Bird and M. G. H. Wallbridge, J . Chein. SOC. (-4), 1967, 661.

3. N. A. Bailey, P. H. Bird, and If. G. H. Wallbridge, Comm., 1965, 438

4. N. A. Bailey, P. H. Bird, and M. G. H. Wallbridge, Chem. Comm., 1966, 286

5. N. A. Bailey, P. H. Bird, and M. G. H. Wallbridge, Inorg. Chem., 1968, in the press.

6. A. R. Emery and R. C. Taylor, Spectrochim. Ada, 1960, 16, 1455.

7. W. C. Price, J. Chem. Phys., 1949, 17, 1044.

8. L. S. Bartell and B. L. Carroll, J. Chem. Phys., 1965, 42, 1135.

9. A. Almenningen, G. Gundersen, and A. Haaland, Acta Chem. Scand., 1968, 22, 328.

10. J. A. Pople, W. G. Schneider, and H. J. Bernstein, ' High Resolution Nuclear Magnetic Resonance, McGraw-Hill, London, 1969, p. 223.

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