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Novel Sequential Batch Electro-Fenton System for Total Kjeldahl Nitrogen Removal: Solution for Highly Polluted Industrial Wastewater

Title:

Novel Sequential Batch Electro-Fenton System for Total Kjeldahl Nitrogen Removal: Solution for Highly Polluted Industrial Wastewater

Fellah Jahromi, Arash ORCID: https://orcid.org/0000-0001-8409-5462 (2017) Novel Sequential Batch Electro-Fenton System for Total Kjeldahl Nitrogen Removal: Solution for Highly Polluted Industrial Wastewater. Masters thesis, Concordia University.

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Abstract

A novel electro-Fenton sequential batch reactor (EF-SBR) was developed in this study which permits to overcome main drawbacks of Fenton process, sludge production. The primary objective of this research is providing a solution for treatment of industrial wastewater containing specifically high amount of Total Kjeldahl Nitrogen (TKN). For sustainable reason, a more detailed objective of this study is simultaneous removal of ammonia, total nitrogen, and organic nitrogen. Thereby, investigations in four phases were conducted to achieve the objectives. The predominant mechanism of this study is electro Fenton oxidation. In Phase 1, fundamental operating parameters were investigated to achieve optimal design for small scale batch system. Throughout phase 2, the medium scale electrokinetic reactor was developed in which the optimal technological parameters were adjusted to scale up process. A multi compartment large scale EK reactor was designed and tested in Phase 3 to optimize the energy consumption. The results of Phase 3 showed above 99% and 99.6% of ammonia and TKN removal by using potent oxidizing agent in an appropriate time interval which leads to an economical retention time. Throughout Phase 4, the EF-SBR (Electro-Fenton Sequential Batch Reactor) was designed to address a industrial situation. The highlights of Phase 4 were reducing retention time of the EF-SBR while obtaining above 99% removal efficiencies for ammonia, TKN, total nitrogen, and organic nitrogen. Conducted research demonstrated the feasibility of proposed method, as well as fractal analysis to find the pathway to construe the transient variations in the target concentrations while analyzing the samples in an adequate number of points over an extended exposure period. The proposed design is sustainable since limits supplying additional chemicals and optimizes energy use. The technology is ready for a full-scale application.

Divisions:Concordia University > Gina Cody School of Engineering and Computer Science > Building, Civil and Environmental Engineering
Item Type:Thesis (Masters)
Authors:Fellah Jahromi, Arash
Institution:Concordia University
Degree Name:M.A. Sc.
Program:Civil Engineering
Date:13 December 2017
Thesis Supervisor(s):Elektorowicz, Maria
Keywords:Total Kjeldahl Nitrogen, Electrokinetics, Industrial wastewater, Fractal analysis, Electro- Fenton, Sequential batch reactor
ID Code:983381
Deposited By: ARASH FELLAH JAHROMI
Deposited On:11 Jun 2018 02:10
Last Modified:08 Jul 2018 00:00

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Chapter 3
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Chapter 4

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Chapter 5
[5-1] Szpyrkowicz, L., Naumczyk, J., Zilio-Grandi , F., “Electrochemical treatment of tannery wastewater using TiPt and Ti/Pt/Ir electrodes”, Water Research, vol. 29, Issue 2, 1995, pp. 517-524
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[5-4] Rimpault, X., “Tool condition monitoring and surface topography analysis during the machining of CFRP composites” (PhD thesis), Polytechnique Montreal, Université de Montréal, Montréal, Canada, 2016
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