Login | Register

Weathering on Coarse Gravel Roads: Modelling Carbon Dioxide Removal in Weathering Processes on Gravel Roads

Title:

Weathering on Coarse Gravel Roads: Modelling Carbon Dioxide Removal in Weathering Processes on Gravel Roads

Barette-Duckworth, Miles ORCID: https://orcid.org/0009-0003-6148-2349 (2025) Weathering on Coarse Gravel Roads: Modelling Carbon Dioxide Removal in Weathering Processes on Gravel Roads. Masters thesis, Concordia Concordia UniversityUniversity.

[thumbnail of BaretteDuckworth_MSc_F2025.pdf]
Preview
Text (application/pdf)
BaretteDuckworth_MSc_F2025.pdf - Accepted Version
Available under License Creative Commons Attribution.
7MB

Abstract

As global atmospheric carbon dioxide levels rise, negative emissions strategies are being researched to rapidly capture and store these emissions. Enhanced rock weathering as a negative emissions strategy has a strong focus on research on agricultural applications, however, the construction and maintenance of gravel roadways represents an under-researched potential form of weathering. This research examines the contributions of gravel roadways in West Bolton, QC to the reduction of atmospheric carbon dioxide levels through chemical weathering. A model was produced using Stella modeling software to simulate the atmospheric carbon dioxide transformation through weathering of the roadway material in the study area. A sieving analysis was performed to determine both the change in rock particle size over time and for the calculation of the available surface area of the road material. A weathering analysis was performed using road material sampled from the roadway and rainwater captured within the study area. Alkalinity readings as the concentration of CaCO3 were obtained during the weathering analysis and using particle size distribution for the surface area along with the annual rainfall data, weathering rates for all three sample sites were calculated. The weathering rates were found to be 1.36x10-6 mol/m2, 2.25x10-6 mol/m2, and 4.11x10-6 mol/m2. Of critical influence on the weathering rate was the volume of annual rainfall. Model simulations using the results of the sieving and weathering analysis found that the carbon transformation using the analysis results corresponded to the modeled results using reference rates. Factors influencing the modeled carbon transformation were found to be mechanical fracturing from annual daily car passage and maintenance frequency over timescales of ten years. This study begins the research on gravel roads as a negative emissions strategy and produces a model that can inform road management decisions.

Divisions:Concordia University > Faculty of Arts and Science > Geography, Planning and Environment
Item Type:Thesis (Masters)
Authors:Barette-Duckworth, Miles
Institution:Concordia Concordia UniversityUniversity
Degree Name:M. Sc.
Program:Geography, Urban & Environmental Studies
Date:25 January 2025
Thesis Supervisor(s):Matthews, HH. Damon and Sklar, Leonard
Keywords:rock weathering, enhanced rock weathering, climate change, carbon dioxide sequestration, road, roadways, gravel roads, gravel roadways, negative emissions strategies, enhanced rock weathering, atmospheric carbon dioxide reduction, chemical weathering, surface area, weathering rates, alkalinity, road maintenance, carbon transformation, road management,
ID Code:995482
Deposited By: MILES BARETTE DUCKWORTH
Deposited On:04 Nov 2025 16:23
Last Modified:04 Nov 2025 16:23

References:

Alberta Transportation. 2000. “Highway Maintenance Guidelines and Level of Service Manual.” https://open.alberta.ca/dataset/84604631-aec2-4a7d-98f3-060ad2ff6fe8/resource/80f63d44-388b-4924-b2a6-d61705fca62c/download/2000-highway-maintenance-guidelines-level-service-manual-2000-06-14.pdf.
B.C. Ministry of Transportation. 2007. “500 - Low Volume Roads Chapter.” In B.C. Supplement to TAC Geometric Design Guide for Canadian Roads, 500i-500.13. BC Ministry of Transportation. https://www2.gov.bc.ca/assets/gov/driving-and-transportation/transportation-infrastructure/engineering-standards-and-guidelines/highway-design-and-survey/tac/tools/low_volume_roads-interim_guidelines.pdf.
Beerling, David J., Euripides P. Kantzas, Mark R. Lomas, Peter Wade, Rafael M. Eufrasio, Phil Renforth, Binoy Sarkar, et al. 2020. “Potential for Large-Scale CO2 Removal via Enhanced Rock Weathering with Croplands.” Nature 2020 583:7815 583 (7815): 242–48. https://doi.org/10.1038/S41586-020-2448-9.
Berner, Robert A. 1978. “Rate Control of Mineral Dissolutions under Earth Surface Conditions.” American Journal of Science 278:1235–52. http://www.ajsonline.org/content/278/9/1235.full.pdf.
Berthelot, Curtis, and Allan Carpentier. 2007. “Gravel Loss Characterization and Innovative Preservation Treatments of Gravel Roads: Saskatchewan, Canada.” Transportation Research Record: Journal of the Transportation Research Board 1819 (1): 180–84. https://doi.org/10.3141/1819b-23.
Bray, Andrew W, Eric H Oelkers, Steeve Bonneville, Domenik Wolff-Boenisch, Nicola J Potts, Gary Fones, and Liane G Benning. 2015. “The Effect of PH, Grain Size, and Organic Ligands on Biotite Weathering Rates.” Geochimica et Cosmochimica Acta 164 (August):127–45. https://doi.org/10.1016/J.GCA.2015.04.048.
CIA. 2017. The World Factbook. 2016th–2017th ed. Central Intelligence Agency. https://doi.org/10.1016/j.petrol.2013.05.007.
ClimateData.ca. n.d. “West Brome QC ClimateData.Ca.” ClimateData.Ca. Accessed August 13, 2024. https://climatedata.ca/explore/location/?loc=EKOAU&location-select-temperature=tx_max&location-select-precipitation=r1mm&location-select-other=frost_days&dataset_name=cmip5.
Colman, Steven M. 1981. “Rock-Weathering Rates as Functions of Time.” Quaternary Research 15 (3): 250–26445. https://doi.org/10.1016/0033-5894(81)90029-6.
Deng, Hang, Eric Sonnenthal, Bhavna Arora, Hanna Breunig, Eoin Brodie, Markus Kleber, Nicolas Spycher, and Peter Nico. 2023. “The Environmental Controls on Efficiency of Enhanced Rock Weathering in Soils.” Scientific Reports 2023 13:1 13 (1): 1–10. https://doi.org/10.1038/S41598-023-36113-4.
Dietzen, Christiana, Robert Harrison, and Stephani Michelsen-Correa. 2018. “Effectiveness of Enhanced Mineral Weathering as a Carbon Sequestration Tool and Alternative to Agricultural Lime: An Incubation Experiment.” International Journal of Greenhouse Gas Control 74 (August):251–58. https://doi.org/10.1016/j.ijggc.2018.05.007.
Dietzen, Christiana, and Minik T. Rosing. 2023. “Quantification of CO2 Uptake by Enhanced Weathering of Silicate Minerals Applied to Acidic Soils.” International Journal of Greenhouse Gas Control 125 (May):103872. https://doi.org/10.1016/J.IJGGC.2023.103872.
DMTI Spatial Inc. 2018. “DMTI CanMap Route Logistics.” Markham: DMTI Spatial Inc.
Earle, Steven. 2015. Physical Geology. Physical Geology. BCcampus. https://opentextbc.ca/geology/chapter/5-2-chemical-weathering/.
Edwards, David P, Felix Lim, Rachael H James, Christopher R Pearce, Julie Scholes, Robert P Freckleton, and David J Beerling. 2017a. “Climate Change Mitigation: Potential Benefits and Pitfalls of Enhanced Rock Weathering in Tropical Agriculture.” Biology Letters 13 (4). https://doi.org/10.1098/rsbl.2016.0715.
Edwards, David P., Felix Lim, Rachael H. James, Christopher R. Pearce, Julie Scholes, Robert P. Freckleton, and David J. Beerling. 2017b. “Climate Change Mitigation: Potential Benefits and Pitfalls of Enhanced Rock Weathering in Tropical Agriculture.” Biology Letters 13 (4). https://doi.org/10.1098/RSBL.2016.0715.
“Emission Facts: Average Carbon Dioxide Emissions Resulting from Gasoline and Diesel Fuel (EPA420-F-05-001).” 2005. www.epa.gov/otaq/greenhousegases.htm.
Frings, Roy M, Holger Schüttrumpf, and Stefan Vollmer. 2011. “Verification of Porosity Predictors for Fluvial Sand-Gravel Deposits.” Water Resources Research 47 (7). https://doi.org/10.1029/2010WR009690.
Hallet, Bernard. 2006. “Why Do Freezing Rocks Break ?” Science 314 (5802): 1092–93. https://doi.org/10.1126/science.1135200.
Haque, Fatima, Rafael M. Santos, and Yi Wai Chiang. 2020. “CO2 Sequestration by Wollastonite-Amended Agricultural Soils – An Ontario Field Study.” International Journal of Greenhouse Gas Control 97 (June):103017. https://doi.org/10.1016/J.IJGGC.2020.103017.
Heberlein, Thomas A. 2013. Navigating Environmental Attitudes. Navigating Environmental Attitudes. Oxford University Press. https://doi.org/10.1093/acprof:oso/9780199773329.001.0001.
Israeli, Yoni, and Simon Emmanuel. 2018. “Impact of Grain Size and Rock Composition on Simulated Rock Weathering.” Earth Surface Dynamics 6 (2): 319–27. https://doi.org/10.5194/esurf-6-319-2018.
Jiang, Hao, Wenjing Liu, Zhifang Xu, Xiaode Zhou, Ziyan Zheng, Tong Zhao, Li Zhou, Xuan Zhang, Yifu Xu, and Taoze Liu. 2018. “Chemical Weathering of Small Catchments on the Southeastern Tibetan Plateau I: Water Sources, Solute Sources and Weathering Rates.” Chemical Geology 500 (August):159–74. https://doi.org/10.1016/j.chemgeo.2018.09.030.
Kantola, Ilsa B, Michael D Masters, David J Beerling, Stephen P Long, and Evan H DeLucia. 2017. “Potential of Global Croplands and Bioenergy Crops for Climate Change Mitigation through Deployment for Enhanced Weathering.” Biology Letters. https://doi.org/10.1098/rsbl.2016.0714.
Kantzas, Euripides P., Maria Val Martin, Mark R. Lomas, Rafael M. Eufrasio, Phil Renforth, Amy L. Lewis, Lyla L. Taylor, et al. 2022. “Substantial Carbon Drawdown Potential from Enhanced Rock Weathering in the United Kingdom.” Nature Geoscience 2022 15:5 15 (5): 382–89. https://doi.org/10.1038/S41561-022-00925-2.
Kasting, J F. 1984. “Comments on the BLAG Model: The Carbonate-Silicate Geochemical Cycle and Its Effect on Atmospheric Carbon Dioxide over the Past 100 Million Years.” American Journal of Science 284 (10): 1175–82. https://doi.org/10.2475/ajs.284.10.1175.
Kennebec County Soil and Water Conservation District, and Maine Department of Environmental Protection Bureaus of Land Resources and Water Quality. 2016. Gravel Road Maintenance Manual: A Guide for Landowners on Camp and Other Gravel Roads. https://www.maine.gov/dep/land/watershed/camp/road/gravel_road_manual.pdf.
Kump, Lee R, Susan L Brantley, and Michael A Arthur. 2000. “Chemical Weathering, Atmospheric CO 2 , and Climate.” Annual Review of Earth and Planetary Sciences 28 (1): 611–67. https://doi.org/10.1146/annurev.earth.28.1.611.
Larkin, Christina S., M. Grace Andrews, Christopher R. Pearce, Kok L. Yeong, David J. Beerling, Joshua Bellamy, Suzan Benedick, et al. 2022. “Quantification of CO2 Removal in a Large-Scale Enhanced Weathering Field Trial on an Oil Palm Plantation in Sabah, Malaysia.” Frontiers in Climate 4 (August):959229. https://doi.org/10.3389/FCLIM.2022.959229/BIBTEX.
Lawford-Smith, H, and A Currie. 2017. “Accelerating the Carbon Cycle: The Ethics of Enhanced Weathering.” Biology Letters 13 (4). https://doi.org/10.1098/rsbl.2016.0859.
Lehmann, Nele, Hugues Lantuit, Michael Ernst Böttcher, Jens Hartmann, Antje Eulenburg, and Helmuth Thomas. 2023. “Alkalinity Generation from Carbonate Weathering in a Silicate-Dominated Headwater Catchment at Iskorasfjellet, Northern Norway.” Biogeosciences 20 (16): 3459–79. https://doi.org/10.5194/BG-20-3459-2023.
May, Matthias M, and Kira Rehfeld. 2019. “ESD Ideas: Photoelectrochemical Carbon Removal as Negative Emission Technology.” Earth System Dynamics 10 (1): 1–7. https://doi.org/10.5194/esd-10-1-2019.
McDonald, Tom, and Bob Sperry. 2014. “Highway Maintenance and Operations Handbook.” http://www.dot.state.ak.us/stwddes/research/assets/pdf/ak_maint-ops_hb.pdf.
Millot, Romain, Jérôme Gaillardet, Bernard Dupré, and Claude Jean Allègre. 2002. “The Global Control of Silicate Weathering Rates and the Coupling with Physical Erosion: New Insights from Rivers of the Canadian Shield.” Earth and Planetary Science Letters 196 (1–2): 83–98. https://doi.org/10.1016/S0012-821X(01)00599-4.
Monlux, Stephen, Michael Mitchell, and S Monlux. 1989. “Chloride Stabilization of Unpaved Road Aggregate Surfacing.” Transportation Research Record: Journal of the Transportation Research Board 2:50–58. https://doi.org/10.3141/1989-48.
Montserrat, Francesc, Phil Renforth, Jens Hartmann, Martine Leermakers, Pol Knops, and Filip J R Meysman. 2017. “Olivine Dissolution in Seawater: Implications for CO2 Sequestration through Enhanced Weathering in Coastal Environments.” Environmental Science and Technology 51 (7): 3960–72. https://doi.org/10.1021/acs.est.6b05942.
Moosdorf, Nils, Phil Renforth, and Jens Hartmann. 2014. “Carbon Dioxide Efficiency of Terrestrial Enhanced Weathering.” Environmental Science and Technology 48 (9): 4809–16. https://doi.org/10.1021/es4052022.
Naimi, Babak, and Alexey Voinov. 2012. “StellaR: A Software to Translate Stella Models into R Open-Source Environment.” Environmental Modelling & Software 38 (December):117–18. https://doi.org/10.1016/J.ENVSOFT.2012.05.012.
National Oceanic and Atmospheric Administration. 2022. “Carbon Dioxide Now More than 50% Higher than Pre-Industrial Levels.” June 3, 2022. https://www.noaa.gov/news-release/carbon-dioxide-now-more-than-50-higher-than-pre-industrial-levels.
Pidgeon, Nick F, and Elspeth Spence. 2017. “Perceptions of Enhanced Weathering as a Biological Negative Emissions Option.” Biology Letters 13 (4). https://doi.org/10.1098/rsbl.2017.0024.
Rastegari Mehr, Meisam, Behnam Keshavarzi, and Armin Sorooshian. 2019. “Influence of Natural and Urban Emissions on Rainwater Chemistry at a Southwestern Iran Coastal Site.” Science of The Total Environment 668 (June):1213–21. https://doi.org/10.1016/J.SCITOTENV.2019.03.082.
Schuiling, R D, and P Krijgsman. 2006. “Enhanced Weathering: An Effective and Cheap Tool to Sequester CO 2.” Climatic Change 74 (1–3): 349–54. https://doi.org/10.1007/s10584-005-3485-y.
Schuiling, Roelof Dirk. 2017. “Olivine Weathering against Climate Change.” Natural Science 09 (01): 21–26. https://doi.org/10.4236/ns.2017.91002.
Skorseth, Ken, Richard Ried, and Katherine Heiberger. 2015. Gravel Roads Maintenance and Design Manual. 2nd ed. Federal Highway Administration (FHWA) and the South Dakota Local Technical Assistance Program (SDLTAP).
Skorseth, Ken, and Ali A Selim. 2000. “Section III: Surface Gravel.” In Gravel Roads: Maintenance and Design Manual, 39–50. US Department of Transportation. https://www.epa.gov/sites/production/files/2015-10/documents/2003_07_24_nps_gravelroads_sec3_0.pdf.
Smith, S M, O Geden, M J Gidden, W F Lamb, G F Nemet, J C Minx, H Buck, et al. 2024. “The State of Carbon Dioxide Removal - 2nd Edition.” The State of Carbon Dioxide Removal. https://osf.io/f85qj/.
Statistics Canada. 2009. “Envirostats.” Statistics Canada. https://www150.statcan.gc.ca/n1/pub/16-002-x/16-002-x2009001-eng.pdf.
Strefler, Jessica, Thorben Amann, Nico Bauer, Elmar Kriegler, and Jens Hartmann. 2018. “Potential and Costs of Carbon Dioxide Removal by Enhanced Weathering of Rocks.” Environmental Research Letters 13 (3): 34010. https://doi.org/10.1088/1748-9326/aaa9c4.
Taksavasu, Tadsuda, Piyanat Arin, Thanakon Khatecha, and Suchanya Kojinok. 2024. “Microtextural Characteristics of Ultramafic Rock-Forming Minerals and Their Effects on Carbon Sequestration.” Minerals 14 (6): 597. https://doi.org/10.3390/MIN14060597/S1.
Taylor, Lyla L, Joe Quirk, Rachel M S Thorley, Pushker A Kharecha, James Hansen, Andy Ridgwell, Mark R Lomas, Steve A Banwart, and David J Beerling. 2016. “Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification.” Nature Climate Change 6 (4): 402–6. https://doi.org/10.1038/nclimate2882.
The Pennsylvania State University. 2018. Driving Surface Aggregate (DSA) Handbook. Penn State University. https://www.dirtandgravel.psu.edu/sites/default/files/General.
White, Art F, and Susan L Brantley. 2003. “The Effect of Time on the Weathering of Silicate Minerals: Why Do Weathering Rates Differ in the Laboratory and Field?” Chemical Geology 202 (3–4): 479–506. https://doi.org/10.1016/j.chemgeo.2003.03.001.
All items in Spectrum are protected by copyright, with all rights reserved. The use of items is governed by Spectrum's terms of access.

Repository Staff Only: item control page

Downloads per month over past year

Research related to the current document (at the CORE website)
- Research related to the current document (at the CORE website)
Back to top Back to top